Access to the full text of this article requires a subscription. There’s a problem loading this menu right now. Product details File Size: In contrast, after immersion of a gold substrate into a solution of 5 or 6 , anchoring of the complexes was clearly evidenced by XPS via the chemical shift of the S—2p binding energy toward lower binding energies. Shopbop Designer Fashion Brands. Amazon Drive Cloud storage from Amazon. The owners of this website hereby guarantee to respect the legal confidentiality conditions, applicable in France, and not to disclose this data to third parties.
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Two approaches have been used to anchor the heterometallic complex on the surface and generate monolayers.
The first process consisted of depositing cluster 5 by spin coating on a gold surface. The second was the immersion of a gold surface into a cluster solution. For both palldaium, the resulting deposits were analysed by STM scanning tunneling microscopyellipsometry and XPS X-ray photoelectron spectroscopy.
SOFT X-RAY EMISSION SPECTRA FROM ALUMINIUM-NIOBIUM AND ALUMINIUM-PALLADIUM ALLOYS
For the layers obtained by spin coating of a solution of cluster 5it was found that the cluster is not attached to the surface, but only deposited on it. In contrast, after immersion of a gold substrate into a solution of 5 or 6anchoring of the complexes was clearly evidenced by XPS via the chemical shift of the S—2p binding energy toward lower binding energies.
Ces couches ont ensuite été analysées par STM Scanning tunneling microscopypar ellipsométrie et par spectroscopie XPS X-ray photoelectron spectroscopy. Mixed-metal clusters, Self-assembly, Gold surfaces, Spectroscopy, Scanning tunneling microscopy, X-ray photoelectron spectroscopy.
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Palladium / Platine
Access to the PDF text. Access to the full text of this article requires a subscription. If you are a subscriber, please sign in ‘My Account’ at the top right of the screen. If you want to subscribe to this journal, see our rates You can purchase this item in Pay Per View: Synthesis of functional heterometallic complexes and clusters containing molybdenum and palladijm or platinum, their self-assembly on gold surfaces and X-ray photoelectron spectroscopic studies.
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Tri-X, X-Ray, Révélateur et Palladium, tests divers – Le blog de la Trichromie
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You can move this window by clicking on the headline. Results and discussion Synthesis and characterization of the heterometallic complexes. Experimental part Preparation of the gold substrates. Electronic supplementary information ESI available: CCDC xfay numbers